Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy
Patent
1976-07-02
1978-07-18
Turer, Richard B.
Chemistry: electrical and wave energy
Processes and products
Processes of treating materials by wave energy
20415914, 20415915, 20415919, 20415922, 260837R, 260836, C08F 800
Patent
active
041013980
ABSTRACT:
A process for hardening (I) a resin which is the reaction Product of a first reaction of a) an epoxy resin which contains at least two epoxy groups with b) an olefinically unsaturated monocarboxylic acid followed by a reaction with c) a carboxylic groups containing component; by copolymerizing said resin (I) with (II) a copolymerizable unsaturated monomer under the action of irradiation of an electron beam, one polycarboxylic acid unit of said carboxylic groups containing component being attached to at least two molecules of the epoxy resin the number of epoxy groups being approximately equal to the sum of the number of free carboxylic groups and the number of anhydride groups, the proportion being 1.25 to 1.5 equivalents of epoxyde per equivalent of unsaturated monocarboxylic acid and about 0.25 to 0.5 mol of carboxylic groups containing compound. The radiation dose may be as low as 0.25 Mrad/g resin. Shaped body which is obtained by the process and which may be a film, fibre or a coating.
REFERENCES:
patent: 3466259 (1969-09-01), Jernigan
patent: 3564074 (1971-02-01), Swisher et al.
patent: 3632861 (1972-01-01), Hargis
patent: 3683045 (1972-08-01), Baldwin
Hesse Wolfgang
Jacobi Paul
Hoechst Aktiengesellschaft
Turer Richard B.
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