Process for forming vinyl ester from carboxylic acid with...

Organic compounds -- part of the class 532-570 series – Organic compounds – Fatty compounds having an acid moiety which contains the...

Reexamination Certificate

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C554S124000

Reexamination Certificate

active

06891052

ABSTRACT:
A process is disclosed for forming a vinyl ester from a carboxylic acid and acetylene in the presence of a zinc carboxylate catalyst, wherein a mixture of carboxylic acid and zinc carboxylate catalyst is formed and the water content of the mixture is reduced to between about 0.02 wt. % and about 0.3 wt. %, prior to introduction of the acetylene into the reactor. Optionally, water is introduced into the reactor during the reaction to hydrate any anhydride by-product of the reaction present in the reactor to carboxylic acid reactant. Water is added during the reaction in an amount that is sufficient to convert the anhydride by-product to carboxylic acid reactant, but does not raise the amount of water in the reaction mixture to a level that will reduce the reactivity of the catalyst or reduce the rate of the vinylation reaction.

REFERENCES:
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patent: 3285941 (1966-11-01), Engel et al.
patent: 3455998 (1969-07-01), Arpe
patent: 3527779 (1970-09-01), Paulis et al.
patent: 3607915 (1971-09-01), Borsboom et al.
patent: 1237557 (1963-03-01), None

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