Process for forming MNOS dual dielectric structure

Coating processes – Electrical product produced – Integrated circuit – printed circuit – or circuit board

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427 94, 427 95, H01L 21316, H01L 21318

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044381573

ABSTRACT:
A process for forming memory quality silicon dioxide and silicon nitride dual-dielectric structures in the same LPCVD furnace system by: forming the silicon dioxide at atmospheric pressure at a temperature of 700.degree.-850.degree. using dry oxygen; heat treating the silicon dioxide layer in ammonia; and forming silicon nitride at 400-600 millitorr and 700.degree.-850.degree. C. using dichlorosilane and ammonia. Optionally, a dielectric layer of silicon oxynitride can be formed on the oxide by using N.sub.2 O, ammonia and dichlorosilane obtaining a memory device with improved retention and endurance.

REFERENCES:
patent: 3924024 (1975-12-01), Naber et al.
patent: 4151537 (1976-04-01), Goldman et al.
patent: 4279947 (1981-07-01), Goldman et al.
W. Kern et al., "Advances in Deposition Processes for Passivation Films", J. Vac. Sci. Tech., vol. 14, No. 5, Sep./Oct. 1977, pp. 1082-1099.
A. Bhattacharyya, "FET Gate Structure for Nonvolatile N-Channel Read-Mostly Memory Device", IBM Tech. Discl. Bull., vol. 18, Nov. 1975, p. 1768.
P. Chen, "Threshold-Alterable Si-Gate MOS Devices", IEEE Trans. on El. Devices, vol. ED-24, No. 5, May 1977, pp. 584-586.

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