Single-crystal – oriented-crystal – and epitaxy growth processes; – Forming from vapor or gaseous state – With decomposition of a precursor
Patent
1995-05-31
1997-11-25
Kunemund, Robert
Single-crystal, oriented-crystal, and epitaxy growth processes;
Forming from vapor or gaseous state
With decomposition of a precursor
117108, 117940, C30B 2518
Patent
active
056907370
ABSTRACT:
A process for growing single crystal epitaxial BaF.sub.2 layers on gallium rsenide substrates by slowly reacting Ba, BaCl.sub.2, Bal.sub.2, BaBr.sub.2, BaF.sub.2 .cndot.BaCl.sub.2, BaF.sub.2 .cndot.BaBr.sub.2, BaF.sub.2 .cndot.BaI.sub.2, BaCl.sub.2 .cndot.BaBr.sub.2, Ba.sub.3 (GaF.sub.6).sub.2, BAH.sub.2, or BaO.sub.2 vapor with a clean, hot GaAs substrate at 500.degree. C. to 700.degree. C. in high vacuum until a uniform, thin (.about.12 .ANG.) layer of reaction product is formed and then vapor depositing BaF.sub.2 onto the reaction layer at room temperature to 400.degree. C. to form the single crystal, epitaxial BaF.sub.2 layer.
REFERENCES:
patent: 5225561 (1993-07-01), Kirlin et al.
patent: 5280012 (1994-01-01), Kirlin et al.
patent: 5435264 (1995-07-01), Santiago et al.
patent: 5453494 (1995-09-01), Kirlin et al.
Chu Tak-Kin
Santiago Francisco
Stumborg Michael
Bechtel, Esq. James B.
Kunemund Robert
The United States of America as represented by the Secretary of
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