Process for forming .alpha.-aminonitriles from carbonyl compound

Details Process for forming .alpha.-aminonitriles from carbonyl compound Process for forming .alpha.-aminonitriles from carbonyl compound

1993-10-13

1994-09-20

Brust, Joseph Paul

Organic compounds -- part of the class 532-570 series

Organic compounds

Nitriles

C07C25330

Patent

active

053490797

ABSTRACT:
.alpha.-aminonitrile compounds can be synthesized by reacting a carbonyl compound, for example an aldehyde, such as, one containing an alkyl group, with a fatty amine hydrohalide, for example, a fatty amine hydrochloride, in the presence of a cyanide source, for example, an alkali metal cyanide.

REFERENCES:
patent: 2164781 (1939-07-01), Platz et al.
patent: 4551526 (1985-11-01), Mai et al.
Stout, et al., J. Org. Chem. (1983), 48, pp. 5369-5373.
Matier, et al., J. Med. Chem. (1973), 16, pp. 901-908.
Mai, et al., Synthetic Communications 15(2), (1985), pp. 157-163.
The Merck Index, 10th Ed., (1983), p. ONR-87.
Shafran, et al., "Synthesis & Properties of .alpha.-Aminonitriles", Russian Chemical Reviews 58(2), (1989), pp. 148-162.

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