Process for forming a ziegler-natta catalyst system having a...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

Reexamination Certificate

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Details

C502S103000, C502S076000, C502S125000, C502S121000, C526S124300, C526S124200, C526S124600

Reexamination Certificate

active

10898739

ABSTRACT:
A pre-catalyst is formed by reacting butylethylmagnesium with an alcohol to form a magnesium alkoxide compound, followed by contacting the magnesium alkoxide compound with a phosphorous compound to form a magnesium alkoxide phosphorous compound mixture. The magnesium alkoxide phosphorous compound mixture is subsequently reacted with TiCl4to form a MgCl2support. The MgCl2support is then contacted with an internal donor while being heated to form a first catalyst slurry, which is then contacted with TiCl4while being heated to form a second catalyst slurry. The second catalyst slurry is next contacted with TiCl4while being heated to form a third catalyst slurry, which is washed and dried, resulting in a highly active pre-catalyst with controlled morphology. The pre-catalyst may be combined with one or more co-catalysts and optionally one or more external electron donors to form an active catalyst system, which may be used for the polymerization of olefins.

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