Coating processes – With post-treatment of coating or coating material – Heating or drying
Reexamination Certificate
2000-11-22
2002-04-30
Cameron, Erma (Department: 1762)
Coating processes
With post-treatment of coating or coating material
Heating or drying
C427S409000, C148S243000, C148S264000, C148S275000
Reexamination Certificate
active
06379750
ABSTRACT:
BACKGROUND OF INVENTION
The present invention relates to a process for improving the adhesion of organic coatings such as paint to metal surfaces, particularly aluminum and aluminum alloys. The process cleans and prepares the metal surfaces such that subsequently applied organic coatings to the metal surfaces, such as paint, adhere to the metal surface in a superior fashion.
A typical cleaning/treatment process for metallic surfaces generally removes residual surface soils and the natural oxide layer found on metallic surfaces. The natural oxide layer will then reform in time. This time will vary depending on the presence of corrosion inhibitors within the process, the environment, and the inherent nature of the substrate being treated. As such, the net result of such a treatment can be the removal of surface contaminants. Although this is desirable, it does not necessarily significantly enhance subsequent bonding of organic adhesives or coatings to the metallic surface. However, bonding can be further improved through the use of processes that clearly affect the surface energy of the metallic surface and that form surface layers that are more uniform and, structurally and chemically stable, than the natural oxide layers. The invention described herein is believed to address these issues and to substantially increase the adhesion of subsequent organic coatings to the treated metal surface.
SUMMARY OF THE INVENTION
The proposed invention teaches the treatment of metal surfaces, particularly aluminum or aluminum alloy surfaces with a process comprising:
1. Contacting the metal surface with an adhesion promoting solution comprising:
(a) anitro sulfonic acid; and
(b) optionally, but preferably a glycol ether.
2. Subsequently applying an organic coating to the metal surface.
The adhesion promoting solution of this invention may also optionally, but preferably, comprise an oxidizing acid other than the nitro sulfonic acid, surfactants, and/or 1, 2 bis (beta-chloroethoxy) ethane.
DETAILED DESCRIPTION OF THE INVENTION
The inventors herein have discovered that treatment of metal surfaces, particularly surfaces of aluminum and aluminum alloys, with a specific process greatly improves the adhesion of subsequently applied organic coatings to such metal surfaces. In order to accomplish this, the inventors propose the following process:
1. Contacting the metal surface with an adhesion promoting solution comprising:
a) a nitro sulfonic acid; and
b) optionally, but preferably, a glycol ether.
2. Subsequently applying an organic coating to the metal surface.
Many metals may be treated with the process of the invention but the inventor has found the process to be particularly useful in preparing aluminum and aluminum alloys for painting. Surprisingly and unexpectedly, the proposed process has been discovered to significantly increase the adhesion of organic layers, such as paints and primers, to the treated metallic surface without the use of a chromate conversation coating. Although a chromate conversation coating may be applied after the process of this invention but before the application of the organic coating, it has surprisingly been found that such a coating is unnecessary. Additionally it has been further surprisingly found that metal surfaces treated with the process of this invention may be effectively painted using paint primers that do not contain chrome species (i.e. non-chrome containing primers). Typically chrome containing primers have been used to improve the corrosion resistance of the coated metal surface, particularly aluminum surfaces. Because of the increased adhesion achievable with this process, non-chrome containing primers may now be effectively utilized without significant decreases in corrosion protection.
The adhesion promoting composition may contain a glycol ether. Preferably the glycol ether will be a lower alkyl ether of ethylene glycol, propylene glycol, polyethylene glycol and polyproplene glycol. Some examples of appropriate glycol ethers include ethylene glycol mono butyl ether, ethylene glycol monomethyl ether, propylene glycol monomethyl ether, diethylene glycol monomethyl ether, diethylene glycol mono-n-butyl ether, diethylene glycol monohexyl ether, triethylene glycol monomethyl ether, other similar glycol ethers and mixtures of any of the foregoing. The concentration of the glycol ether may range from 2 to 40 percent by weight but is preferably from 10 to 20 percent by weight. Ethylene glycol mono-butyl ether, commonly marketed under the tradename Butyl Cellosolve, is a preferred glycol ether.
The adhesion promoting composition contains a nitro sulfonic acid. Examples of useful nitro sulfonic acid include p-nitro benzene sulfonic acid, M-nitrobenzene sulfonic acid, 2-chloro-5 nitrobenzene sulfonic acid, 2, 4 dinitrobenzene sulfonic acid, p-nitrotoluene sulfonic acid, 3, 5 dinitro-p-toluene sulfonic acid and the like. The concentration of the nitrosulfonic acid may range from 2 to 10 percent by weight but is preferably from 3 to 8 percent by weight.
The adhesion promoting composition of the proposed process optionally contains 1, 2-bis (beta-chloroethoxy) ethane at a concentration of from 0.1 to 10 percent by weight. Preferably the concentration of 1, 2-bis (beta-chloroethoxy) ethane is from 0.5 to 2.0 percent by weight. 1, 2-bis (beta-chloroethoxy) ethane is only sparingly soluble in water, however a glycol ether, or equivalent substance or solvent, may be utilized to increase the solubility of 1, 2-bis (beta-chloroethoxy) ethane in the adhesion promoting composition.
The adhesion promoting composition may contain an oxidizing acid other than the nitro sulfonic acid. As indicated, the composition will also comprise a nitro sulfonic acid. The nitro sulfonic acid may also act as the oxidizing acid. The oxidizing acid is preferably nitric acid and/or a nitro sulfonic acid but most preferably both nitric acid and a nitro sulfonic acid are utilized in combination. The concentration of the oxidizing acid may range from 0.1 to 20 percent by weight, but is preferably from 0.1 to 10 percent by weight. If nitric acid is utilized in combination with a nitro sulfonic acid, then the concentration of nitric acid (69%) is preferably from 0.1 to 2 percent by weight and the concentration of the nitrosulfonic acid is from 2 to 8 percent by weight.
The adhesion promoting composition may also contain surfactants or water soluble polymers. The inventors have found that the addition of non-ionic surfactants and water soluble polymers are advantageous to the performance of the adhesion promoting composition. In particular homopolymers or copolymers of ethylene oxide and/or propylene oxide have been found to be useful. In addition non-ionic surfactants have also proven to be useful. The concentration of surfactant and water soluble polymers in the adhesion promoting composition may range from 0.5 to 3 percent by weight but is preferably from 1 to 2 percent by weight.
Finally, it may be advantageous to incorporate thickeners into the formulation, if the adhesion promoting composition is to be applied to vertical surfaces. A variety of thickness, such as fumed silica, is known in the art.
As noted, although a chromate conversation coating may be employed after the treatment of this process and before the application of the organic coating, it has surprisingly been discovered that a chromating step is unnecessary and that increased and acceptable adhesion can be achieved without the need for an intermediate chromating step. The elimination of a chromating step is advantageous from economical, environmental and safety points of view. However, if desired, intermediate chromating may be utilized. If desired, the chromating composition to be used in the process can be any composition capable of effectively creating a chromate conversion coating on the surface of the metal being treated. In this regard the teachings of U.S. Pat. No. 2,796,370 are herein incorporated by reference in their entirety. The inventors have found Iridite 14-2, a chromating solution available from MacDermid,
Jenkins Melvin R.
Wojcik Gerald
Cameron Erma
Carmody & Torrance LLP
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