Process for enhancing solubility and reaction rates in...

Semiconductor device manufacturing: process – Chemical etching – Liquid phase etching

Reexamination Certificate

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C438S753000, C257SE21219, C134S001300

Reexamination Certificate

active

07598181

ABSTRACT:
Processes for enhancing solubility and the reaction rates in supercritical fluids are provided. In preferred embodiments, such processes provide for the uniform and precise deposition of metal-containing films on semiconductor substrates as well as the uniform and precise removal of materials from such substrates. In one embodiment, the process includes, providing a supercritical fluid containing at least one reactant, the supercritical fluid being maintained at above its critical point, exposing at least a portion of the surface of the semiconductor substrate to the supercritical fluid, applying acoustic energy, and reacting the at least one reactant to cause a change in at least a portion of the surface of the semiconductor substrate.

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Brian S. Hoyle and Stephen P. Luke, Ultrasound In The Process Industries, Engineering Science and Education Journal, Jun. 1994, pp. 119-122.
C. Horst et al., Activated Solid-Fluid Reactions In Ultrasound Reactors, Chemical Engineering Science 54 (1999), pp. 2849-2858, Institut fur Chemische Verfahrenstechnik, Technische Universitiat Clausthal, LeibnizstraBe 17, D-38678 Clausthal-Zellerfeld, Germany.
Leigh Hagenson Thompson et al., The Rate Enhancing Effect of Ultrasound by Inducing Supersaturation in A Solid-Liquid System, Chemical Engineering Science 55 (2000), pp. 3085-3090.

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