Process for elution of actinide metal microspheres

Compositions – Organic luminescent material containing compositions – Scintillating or lasing compositions

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264 5, G21C 362

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040382028

ABSTRACT:
Actinide metal microspheres are washed with an aqueous solution of a hydrophilic surfactant having an HLB value greater than 10 and up to about 14 to remove water soluble salts therefrom and any water immiscible organic liquids adhering to the microspheres according to the process disclosed. The microspheres are prepared by dispersing an aqueous phase of the appropriate actinide metal oxide into an immiscible organic liquid in the presence of ammonia or an ammonia releasing agent under solidification conditions to form the microspheres. Uranyl nitrate and anion-deficient uranyl nitrate solutions are preferred. Improved results are obtained when the organic liquid contains a complementary lipophilic surfactant having a HLB value of no more than about 10.

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patent: 3586742 (1971-06-01), Chin et al.
patent: 3669632 (1972-06-01), Kanij et al.
Chem. Abstracts No. 70:98067v.
Griffen, W.C., "Classification of Surface Active Agents by HLB," Journal of the Society of Cosmetic Chemists, vol. 1, (1949), pp. 311-326.
Griffen, W.C., "Calculation of HLB Values of Non-Ionic Surfactants" Amer. Perf. & Essential Oil Review, May 1955, pp. 26-29.
Handbook of Chem. and Phys., The Chemical Rubber Co., Cleveland, 1968, p. c-439.
Netherlands Application No. 71,10985 to Imperial Chemical Industries Ltd., Feb. 15, 1972.

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