Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component
Patent
1992-10-09
1994-02-22
Heller, Gregory A.
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Nitrogen or nitrogenous component
423238, 558319, 558320, C01C 300
Patent
active
052884732
ABSTRACT:
A process for the substantial or complete elimination of ammonium sulfate generated during the production of acrylonitrile by the direct ammoxidation of propylene/propane, ammonia and an oxygen containing gas (e.g. air) over a fluid bed catalyst wherein the improvement comprises introducing an organic compound(s) into said reactor at a location where the compound(s) reacts with substantially all of the excess ammonia without affecting the acrylonitrile yield. Preferably, the organic compound is methanol which is introduced into the reactor at below its coking temperature.
REFERENCES:
patent: 3911089 (1975-10-01), Shiraishi et al.
Patent Application No. 1978-35,232 (Japanese), Oct. 2, 1979.
Patent Application No. 1974-87,474 (Japanese)--51-016615, Apr. 17, 1979.
Derwent World Patent Index, JP 51 16615.
Bigler Kenneth L.
Bott Paul E.
Friedrich Maria S.
Keckler Kenneth P.
Kojancic Frank J.
Esposito Michael F.
Heller Gregory A.
The Standard Oil Company
Untener David J.
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