Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge
Patent
1977-05-04
1979-02-27
Tufariello, T. M.
Chemistry: electrical and wave energy
Processes and products
Electrostatic field or electrical discharge
204106, 204108, 204277, C25C 112, C25C 122, C25D 2110
Patent
active
041418042
ABSTRACT:
A process and an apparatus for electrowinning metal from metal bearing solutions is disclosed. A support solution containing a predetermined metal concentration is continuously recirculated through a cell having a porous grid supporting a bed of particulate conducting particles at a sufficiently high flow rate so as to fluidize and expand the bed by 5 to 25%. A gas is continuously fed through the bed of conducting particles so as to strongly agitate the particles at low bed expansion to maintain good mixing and uniform fluidization of the bed of particles. The cell includes an electrode arrangement suspended from the top of the cell and immersed into the bed of fluidized conducting particles. Such electrode arrangement consists of at least one cathode feeder electrode in physical contact with the fluidized particles to make the particles cathodic and so cause the metal ions to deposit on the particles, and at least one anode electrode separated from the cathodic particles by a membrane which allows the free passage of ions while preventing physical contact with the particles. To make the process continuous or semi-continuous, the cell has an inlet for adding small seed particles and an outlet adjacent to the bottom for withdrawing large product particles.
REFERENCES:
patent: 3654098 (1972-04-01), Backhurst et al.
patent: 3703446 (1972-11-01), Haycock et al.
patent: 3787293 (1974-01-01), Kametani
patent: 3941669 (1976-03-01), Bharucha et al.
patent: 3956086 (1976-05-01), Wilkinson et al.
Avedesian Michael M.
Holko Anthony P.
Noranda Mines Limited
Tufariello T. M.
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