Process for electrolysis of aqueous alkali metal halide solution

Chemistry: electrical and wave energy – Processes and products

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204296, C25B 146, C25B 1308

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active

041233360

ABSTRACT:
An aqueous alkali metal halide solution is electrolyzed in an electrolytic cell using a cation exchange membrane which is a fluorocarbon polymer containing sulfonic acid groups and at least one cation exchange group which is less acidic than the sulfonic acid group with higher proportion of the latter in surface stratum on the cathode side of the membrane than in the entire membrane, while controling proton concentration in the anolyte at not higher than critical proton concentration at which no substantial amount of protons in the anolyte penetrate into the membrane.

REFERENCES:
patent: 3909378 (1975-09-01), Walmsley
patent: 3944477 (1976-03-01), Argade
patent: 3960697 (1976-06-01), Kircher et al.
patent: 4024043 (1977-05-01), Dege et al.

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