Process for effecting allylic oxidation

Details Process for effecting allylic oxidation Process for effecting allylic oxidation

1999-01-11

2000-08-29

Dees, Jose' G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Cyclopentanohydrophenanthrene ring system containing

552542, 540 31, 568232, 568326, 560129, C07J 100, C07J 900, C07J 2100, C07C 4500

Patent

active

06111118&

ABSTRACT:
A procedure for oxidizing organic compounds having allylic hydrogen atom(s) involving the steps of reactively contacting the organic compound with a combination of a periodic acid or metal periodate and an alkyl hydroperoxide under conditions of normal as well as elevated pressure of a suitable gas like air. The reaction can conveniently be conducted at temperatures between about 0-65.degree. C. in a cosolvent system of water and organic solvent(s).

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