Process for dyeing uniformly polyacrylonitrile fiber materials

Bleaching and dyeing; fluid treatment and chemical modification – Dye or potential dye composition – additive – treatment,... – Mixed dyes – noncomplexed

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8644, 8927, D06P 370, C09B 2700

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active

042525357

ABSTRACT:
A dyeing process has been found which enables to dye uniformly polyacrylonitrile fiber materials, by using as dyestuffs basic azo dyestuffs being non-quarternized and containing neither cationic quaternary ammonium groups nor cationic N-substituted or N-unsubstituted iminium groups, said azo dyestuffs containing on the other hand at least one unsubstituted or substituted amino group, hydrazino group, amidino group or guanidino group capable of forming salts. The very dyeing process as such is carried out according to usual processing data for dyeing polyacrylonitriles in a slightly acid medium. Especially with the use of several of these dyestuffs for polychromic dyeing, such as trichromic dyeing, special advantages are obtained, insofar that even at cut-rate dyeing periods and for preparing light color shades, there are obtained even dyes with constant color shades, when using these dyestuffs having good migrating properties.

REFERENCES:
patent: 2906747 (1959-09-01), Wolfrum
patent: 3042648 (1962-07-01), Lewis
patent: 4181499 (1980-01-01), Koller et al.
Venkataraman; K., "The Chemistry of Synthetic Dyes", vol. IV, (Academic Press), 1971, pp. 161-165, 206-208.
Colour Index, vol. 4 (Third Edition), 1971, p. 4019, C.I. 11270.

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