Process for dyeing anodized aluminum

Chemistry: electrical and wave energy – Processes and products

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204 42, C25D 1122

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active

050645129

ABSTRACT:
Substituted diphenols, phenyl ethers containing two oxygen atoms attached to a benzene nucleus, and naphthols are more practically effective than previously known additives in stabilizing tin (II) salts, in electrolyte solutions useful for coloring anodized aluminum by electrolysis therein, against oxidation to tin(IV) by reaction with ambient oxygen. Preferred additives include 2-tert-butyl-1,4-dihydroxybenzene, methylhydroquinone, trimethylhydroquinone, 4-hydroxynaphthalene-2,7-disulfonic acid, and p-hydroxyanisole. If p-toluenesulfonic acid or napthalene sulfonic acid are also used in the electrolyte, the throwing power can be greatly improved.

REFERENCES:
patent: 3769180 (1971-12-01), Gedde
patent: 3849263 (1970-06-01), Gedde
patent: 4042468 (1976-03-01), Hasegawa et al.
patent: 4401525 (1979-11-01), Ruf
S. Wernick et al., Die Oberflaechenbehandlung von Aluminium, 2nd Ed., 1977, p. 364.
S. A. Pozzoli et al., Korrosionsschutz Alum., Verants. Eur. Foed Korros, Vortr. 88th, 1976, pp. 139-145.
Metal Finishing Abstracts, vol. 23 (1981), Jan./Feb., No. 1, Teddington, Middlesex, England.

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