Process for direct carbonylation of hydrocarbons

Details Process for direct carbonylation of hydrocarbons Process for direct carbonylation of hydrocarbons

1987-11-24

1990-02-13

Niebling, John F.

Chemistry: electrical and wave energy

Processes and products

Processes of treating materials by wave energy

2041579, 20415793, B01J 1908

Patent

active

049004131

ABSTRACT:
A process is disclosed, for the manufacture of carbonylated products and/or olefins by reacting hydrocarbons with carbon monoxide in the presence of a transition metal complex, under irradiation with light.

REFERENCES:
patent: 2485237 (1949-10-01), Gresham
patent: 4487972 (1984-12-01), Haag
Kunin et al., "Photochemical Carbonylation of Benzene by Iridium(I) and Rhodium(I) Square-Planar Complexes", J. Am. Chem. Soc. 1986, 108, 535-536.
Fisher et al., "Carbon-Hydrogen Bond Activation Using a Bis(phosphine)-Iridium Carbonyl Hydride and the Carbonylation of Benzene", pp. 764-767, Organometallics, vol. 2, No. 6, 1983.

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