Process for determining a molecular weight distribution in a...

Data processing: measuring – calibrating – or testing – Measurement system in a specific environment – Chemical analysis

Reexamination Certificate

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C526S060000

Reexamination Certificate

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07917308

ABSTRACT:
The invention relates to a process for determining a molecular weight distribution in a polymer. When a polymer is prepared, chains of different length are formed. Correspondingly, a distribution of the molecular weights of the chains of a polymer arises.It is an object of the invention to be able to determine the molecular weight distribution in an improved manner compared to the prior art.The object of the invention is achieved by describing starting data G*(ω) available in numerical form, i.e. the complex shear modulus measured as a function of frequency or the mastercurve constructed therefrom, are described by an analytical function. In this way, exact knowledge of the relaxation behaviour is available in improved form, in particular also in the case of prolonged relaxation times. This enables a valid determination of the relaxation time spectrum and hence a fundamentally more valid calculation of the molecular weight distribution.

REFERENCES:
patent: 7427506 (2008-09-01), Garcia-Franco et al.
Peirotti et al. [Latin American Applied Research, 33:185-194 (2003)].
W. Thimm et al., “An Analytical relation between relaxation time spectrum and molecular weight Distribution”, J. Rheol. 43 No. 6 (1999) 1663-1672.
Cole, R., Cole, H. J, Chem. Phys., 9:341, 1941 “Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics”.
Rouse, P.E., J. Chem. Phys., 21:1272, 1953 A Theory of the Linear Viscoelastic Properties of Dilute Solutions of Coiling Polymers.

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