Process for desulfurization of residua with sodamide-hydrogen an

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Hydrogenation

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208209, 208230, 208235, C10G 2300

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active

040173810

ABSTRACT:
Sulfur-containing petroleum oil feedstocks which include heavy hydrocarbon constituents undergo simultaneous desulfurization and hydroconversion by contacting and reacting such feedstocks with sodamide in the presence of hydrogen and at elevated temperatures. The mixture of reaction products resulting from the above procedure is separated to give a sodium sulfur salt by-product, and a petroleum oil product which has been substantially desulfurized and demetallized, as well as being significantly improved as indicated by a reduced Conradson carbon content and an increased API gravity relative to the feedstock. Sodamide is regenerated from the sodium sulfur salt by-product and can be recycled for reaction with additional feedstock.

REFERENCES:
patent: 1729943 (1929-10-01), Hofsass et al.
patent: 1937914 (1933-12-01), Pines
patent: 3470086 (1969-09-01), Jones
patent: 3787315 (1974-01-01), Bearden et al.

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