Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1991-02-12
1992-06-23
Evans, J. E.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
5689098, 568917, C07C 2988, C07C 29132, C07C 3112
Patent
active
051244926
ABSTRACT:
This invention relates to a process for removing peroxide impurities contained in a tertiary butyl alcohol feedstock. The process involves contacting the feedstock with an iron (II) compound such as iron (II) chloride, under an inert atmosphere at elevated pressures and temperatures for a time sufficient to reduce the peroxides to alcohols and oxidize the iron (II) to iron (III). The iron (II) compound may be added in a homogeneous phase or it may be deposited on a support. When the iron (II) is added as a homogeneous phase, it is separated from the product by contacting the mixture with a cation exchange column. Finally, when a supported iron (II) compound is used, the process may be run in a batch or continuous mode.
REFERENCES:
patent: 2993072 (1961-07-01), Chiusoli et al.
patent: 3470239 (1969-09-01), Russell
patent: 3474151 (1969-10-01), Grane
patent: 4547598 (1985-10-01), Sanderson et al.
patent: 4551553 (1985-11-01), Taylor et al.
patent: 4704482 (1987-11-01), Sanderson et al.
patent: 4705903 (1987-11-01), Sanderson et al.
patent: 4742179 (1986-11-01), Sanderson
patent: 4922034 (1990-05-01), Sanderson et al.
patent: 4922036 (1990-05-01), Sanderson et al.
patent: 4973380 (1989-10-01), Sanderson et al.
patent: 4992602 (1991-02-01), Sanderson et al.
patent: 5025113 (1991-06-01), Sanderson et al.
Jan Chwu-Ching
Malloy Thomas P.
Evans J. E.
McBride Thomas K.
Molinaro Frank S.
Snyder Eugene I.
UOP
LandOfFree
Process for decomposing peroxide impurities in a tertiary butyl does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Process for decomposing peroxide impurities in a tertiary butyl , we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for decomposing peroxide impurities in a tertiary butyl will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-934324