Process for converting thallium (I) to thallium (III)

Details Process for converting thallium (I) to thallium (III) Process for converting thallium (I) to thallium (III)

1977-04-21

1978-09-19

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

423395, 423495, 423544, 423659, C01F 500

Patent

active

041154193

ABSTRACT:
A monovalent thallium compound is converted to a trivalent thallium compound by treating the thallium (I) compound with an organic hydroperoxide in the presence of a Group VIII noble metal catalyst in a liquid medium and in the presence of a promoter comprising a member selected from the group consisting of alkali metal compounds and heterocyclic tertiary amines, to oxidize the thallium (I) compound to a thallium (III) compound.

REFERENCES:
patent: 3399956 (1968-09-01), Hirose et al.
patent: 3436409 (1969-04-01), Hill et al.
patent: 3479262 (1969-11-01), MacLean et al.
patent: 3816540 (1974-06-01), Barone et al.
Spencer, L. Anorg. Chem. v44, pp. 399-407 (1905).

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