Process for converting olefins to gasoline, distillate and alkyl

Chemistry of hydrocarbon compounds – Plural serial diverse syntheses – With hydrocarbon effluent stream splitting for recycle to...

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585331, 585332, 585415, 585533, 585709, 585733, 585723, C07C 200

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046330275

ABSTRACT:
A continuous process for upgrading C.sub.3 -C.sub.4 hydrocarbon feed containing olefins to produce heavier liquid hydrocarbons comprising converting a major portion of C.sub.3 -C.sub.4 olefins in an oligomerization zone by contacting a shape selective medium pore zeolite catalyst at elevated temperature and pressure to make distillate and olefinic gasoline; fractionating the oligomerization stage effluent to provide distillate and gasoline product and a C.sub.3 -C.sub.4 intermediate stream containing isobutane and unconverted propene and butylene; and combining the C.sub.3 -C.sub.4 intermediate stream with a portion of C.sub.3 -C.sub.4 feed and further converting the combined streams in an alkylation zone to make heavier paraffinic hydrocarbons.
The olefin feed may be produced by catalytically converting methanol or similar oxygenated hydrocarbons in a known process.

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