Process for converting lower alkanes to esters

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis

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585469, 585638, 585733, 585943, 560302, 560304, 560305, 560318, C07C 200

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052331130

ABSTRACT:
This invention is a process for converting lower alkanes into their corresponding esters and optionally into various intermediates (such as methanol) and other liquid hydrocarbons. The alkanes are oxidatively converted to oxy-esters at high selectivity using catalytic amounts of a Group VIII noble metal. If so desired, the alkyl oxy-esters may be converted to alcohols or other intermediates such as alkyl halides. The oxy-esters, alcohols, and other intermediates may optionally be converted to liquid hydrocarbons such as gasoline.

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