Process for converting CO and H.sub.2 O into hydrocarbons using

Chemistry: fischer-tropsch processes; or purification or recover – Group viii metal containing catalyst utilized for the...

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585733, C07C 102, C07C 110

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active

042697840

ABSTRACT:
A homogeneous process for preparing hydrocarbons from CO and H.sub.2 O, D.sub.2 O or T.sub.2 O employing a soluble ruthenium catalyst. The process comprises contacting CO and H.sub.2 O, D.sub.2 O or T.sub.2 O in the presence of a homogeneous aqueous solution containing a catalytically effective amount of a water-soluble ruthenium compound and heating the solution to temperatures of from 200.degree. to 500.degree. C. at pressures of from 0.1 to 100 MPa, the products are C.sub.9 to C.sub.60 hydrocarbons.

REFERENCES:
patent: 2632014 (1953-03-01), Gresham
patent: 2786863 (1957-03-01), Kolbel et al.
patent: 3055949 (1962-09-01), Howk et al.
Kolbel, Die Makromoleinlare Chemie, Bosel, 70 (1964) pp. 1-11.
Halpern et al., J.A.C.S., 83, pp. 4097-4098 (1961).

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