Chemistry: fischer-tropsch processes; or purification or recover – Group viii metal containing catalyst utilized for the...
Patent
1979-10-15
1981-05-26
Mars, Howard T.
Chemistry: fischer-tropsch processes; or purification or recover
Group viii metal containing catalyst utilized for the...
585733, C07C 102, C07C 110
Patent
active
042697840
ABSTRACT:
A homogeneous process for preparing hydrocarbons from CO and H.sub.2 O, D.sub.2 O or T.sub.2 O employing a soluble ruthenium catalyst. The process comprises contacting CO and H.sub.2 O, D.sub.2 O or T.sub.2 O in the presence of a homogeneous aqueous solution containing a catalytically effective amount of a water-soluble ruthenium compound and heating the solution to temperatures of from 200.degree. to 500.degree. C. at pressures of from 0.1 to 100 MPa, the products are C.sub.9 to C.sub.60 hydrocarbons.
REFERENCES:
patent: 2632014 (1953-03-01), Gresham
patent: 2786863 (1957-03-01), Kolbel et al.
patent: 3055949 (1962-09-01), Howk et al.
Kolbel, Die Makromoleinlare Chemie, Bosel, 70 (1964) pp. 1-11.
Halpern et al., J.A.C.S., 83, pp. 4097-4098 (1961).
Exxon Research & Engineering Company
Mars Howard T.
Takemoto James H.
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