Process for conversion of crude hydrocarbon mixtures

Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – Hydrocarbon is contaminant in desired hydrocarbon

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585259, 568688, 568689, 568697, C07C 4108, C07C 4300, C07C 508, C07C 7167

Patent

active

056000456

ABSTRACT:
A process for conversion of crude hydrocarbon mixtures comprising tertiary olefins and gum-forming constituents with an alcohol in the presence of hydrogen, which process comprises contacting the crude hydrocarbon mixture, the alcohol, and hydrogen with a catalyst comprising an acidic molecular sieve containing an active hydrogenation metal component, as well as a stabilized crude hydrocarbon mixture containing alkyl tertiary alkyl ethers. A process for conversion of a tertiary olefin which contains one or more additional ethylenically or acetylenically unsaturated bonds.

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patent: 5084070 (1992-01-01), Kohler et al.
patent: 5489719 (1996-02-01), Le et al.
Ind. Eng. Chem. Res., Preparation of Methyl tert-Buryl Ether (MTBE) Over Zeolite Catalyst, Pochen Chu and Gunter H. Kuhl, 1987, 26, pp. 365-369.
Chem. Eng. Comm., Synthesis of Methyl Tertiary-Butyl Ether on HZSM-5 Zeolite, S. I. Pien and W. J. Hatcher, 1990, 93, pp. 257-265.
Chemical Engineering, Multi-Ether Processes Boost Gasoline Octane, Herb Short, Jun. 23, 1986 pp. 34-35.
Erd ol and Kohle-Erdgas, Petrochemie vereinigt mit brennstoff-Chemie, Novel Catalyst Widens Octane Opportunities, G. Pritchard and B. Schleppinghoff, Bd. 41, Heft 4, Apr., 1988, pp. 157-160.

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