Process for continuous controlled alcoholysis of polyvinyl aceta

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525 56, 525 60, C08F 812

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active

043384056

ABSTRACT:
Improved process for the preparation of partially alcoholyzed polyvinyl acetate having good compositional uniformity comprises rapid premixing of the polyvinyl acetate polymer and base catalyst solutions in a static mixer and carrying out the alcoholysis reaction in an intermeshing, self-wiping, twin-rotor mixer or mixing extruder. The process yields polyvinyl alcohol product having a maximum hot water insoluble fraction of about 1.1% by weight obtained by the proper adjustment of the feed temperature, the shear rate in the premixer and the catalyst concentration in the catalyst feed solution.

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patent: 3300460 (1967-01-01), Vacca
patent: 3386981 (1968-06-01), Akaboshi et al.
patent: 3471131 (1969-10-01), Fritzweiler et al.

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