Process for concurrent esterification and separation using a sim

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

560234, C07C 6702

Patent

active

054059925

ABSTRACT:
A process for the continuous esterification of at least one alcohol and at least one carboxylic acid to form at least one ester and water, and the concurrent separation of the esterification products has been developed. The process uses a solid bed which as a catalyst for esterification and as an adsorbent for at least one of the products. The process preferably operates in the simulated moving bed mode. A specific embodiment of the invention is one where the simulated moving bed is a homogeneous mixture of at least one solid effective as an esterification catalyst and at least one solid effective as an ester or water adsorbent. Another specific embodiment is one where the simulated moving bed is a strongly acidic macroreticular polymeric resin effective both as an esterification catalyst and as an adsorbent for at least one esterification product.

REFERENCES:
patent: 4008291 (1977-02-01), Zabransky et al.
patent: 4028430 (1977-07-01), Stine et al.
patent: 4435595 (1984-03-01), Agreda et al.
patent: 4777303 (1988-10-01), Kitson et al.
patent: 4826795 (1989-05-01), Kitson et al.
patent: 5032523 (1991-07-01), Amano et al.
patent: 5126055 (1992-06-01), Yamashita et al.
patent: 5149680 (1992-09-01), Kitson et al.
patent: 5151547 (1992-09-01), Sato et al.
Vaporclyan, G. G.; Kadlec, R. H.; AlChE Journal, 1987, 33(8), 1334-1343.
Fish, B. B.; Carr, R. W.; Chem. Eng. Sci., 1989 44, 1773-1783.
Carr, R. W.; Preparative and Production Scale Chromatography, Ganetsos, G. and Barker, P. E., Eds., Chromatographic Science Series, vol. 61, Marcel Decker: New York, 1003, Chapter 18, pp. 443-446-1989.
Sardin, M., Villermaux, J., Nouv. J. Chim., 1979 3(4), 255-261.
Sardin, M., Schweich, D., Villermaux, J., Preparative and Production Scale Chromatography, Ganetsos, G., Barker, P. E., Eds., Chromatographic Science Series, vol. 61, Marcel Dekker: New York, 1993, Chap. 20, pp. 502-508.
Ray, A., Tonkovich, A. L., Aris, R., Carr, R. W., Chem Eng. Sci., vol. 45. No. 8, pp. 2431-2437 (1990).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Process for concurrent esterification and separation using a sim does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for concurrent esterification and separation using a sim, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for concurrent esterification and separation using a sim will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-1539730

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.