Process for comminuting and activating limestone by reaction wit

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

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423430, 241 1, B02C 1900, C01B 1100, C01F 524

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active

042724988

ABSTRACT:
The present invention relates to a non-mechanical method of converting coarsely ground limestone to a very fine powder. A slurry of ground calcium carbonate or limestone is contacted with carbon dioxide gas at high pressure to convert the solids in the slurry to an unstable form. The carbon dioxide pressure is then instantaneously released to form a slurry of activated calcium carbonate particles substantially reduced in size. This activated calcium carbonate slurry may be used to scrub flue gases.

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patent: 3906078 (1975-09-01), Hausberg et al.
Johnston et al., The Complete Solubility Curve of Calcium Carbonate, J.A.C.S., 38, pp. 975-983, (1916).
McCoy et al., Equilibrium Between Alkali Earth Carbonates, Carbon Dioxide and Water, J.A.C.S., 33, pp. 465-473, (1911).
U.S. Bureau of Mines Report of Investigation, #3480, p. 62.
Gross et al., Explosive Shamering as a Possible Economical Method of Ore Prepartion, U.S. Bureau of Mines Report of Investigation, #3268, pp. 11-19.

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