Coating processes – With pretreatment of the base – Preapplied reactant or reaction promoter or hardener
Patent
1981-06-29
1983-01-11
Smith, John D.
Coating processes
With pretreatment of the base
Preapplied reactant or reaction promoter or hardener
427306, 4274431, 427307, 106 127, C23C 302
Patent
active
043682219
ABSTRACT:
The invention relates to a process for coating fibrous glass with a glass metal mainly consisting of nickel-phosphorus, under conditions free of current. According to the process a fibrous glass substrate is treated with an aliphatic alcohol having 1 to 4 carbon atoms and subsequently with an aqueous solution of SnCl.sub.2, in the presence of hydrochloric acid, and is then activated with a solution of palladium chloride in aqueous hydrochloric acid. Thereafter the pretreated and activated substrate is kept in a bath comprising nickel ammonium sulfate or nickel sulfate and nickel ammonium sulfate as a nickel-containing component, in combination with sodium hypophosphite, an alkali metal salt of at least one organic acid having a low molecular weight, a mineral acid, preferably sulfuric acid or hydrochloric acid in an amount sufficient to adjust the pH to 3 to 4, and optionally organic or inorganic metal-deposition regulating agent(s) at a temperature between 50.degree. to 90.degree. C.
REFERENCES:
patent: 2690402 (1954-09-01), Crehan
patent: 3060059 (1962-10-01), Sickles
patent: 3476594 (1969-11-01), Soderberg
patent: 3686020 (1972-08-01), Colt-Palagos
patent: 4086128 (1978-04-01), Sugio
Vetrotex International, (Brochure, p. 4), .COPYRGT.1975, Geneva, Switzerland.
"Metallic Glasses", by American Society for Metals, (1978).
Wein, "Nickel and Cobalt Films, " The Glass Industry, Sep. 1959, pp. 476, 477, 498, 500-502.
Bagi nee Schmidt Terezia
Dorner Henrik
Fuzesi Pal
Hegedus Zoltan
Kanyo Miklos
Bacs Megyei Allami Epitoipari Vallalat
Csepel Muvek Tervezo es Kutato Intezete
Katona Gabriel P.
Smith John D.
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