Process for chlorinating C.sub.8 to C.sub.30 linear hydrocarbons

Details Process for chlorinating C.sub.8 to C.sub.30 linear hydrocarbons Process for chlorinating C.sub.8 to C.sub.30 linear hydrocarbons

1975-08-06

1977-10-04

Higel, Floyd D.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260663, 260864, 526 72, C07C 1702, C07C 1708, C07C 1710

Patent

active

040524710

ABSTRACT:
An improved process for chlorinating substantially linear, liquid C.sub.8 to C.sub.30 hydrocarbons by intimately mixing the hydrocarbons and water in a weight ratio of 0.09:1 to 10:1, feeding the mixture of hydrocarbon and water to a reactor, adding 2 to 20 moles of chlorine per mole of hydrocarbon to the mixture in countercurrent flow to the mixture at a rate of 20 to 600 grams per hour per kilogram of hydrocarbon at 50.degree. to 150.degree. C for .5 to 10 hours and recovering chlorinated hydrocarbons.

REFERENCES:
patent: 2022619 (1935-11-01), Gallsworthy
patent: 2763699 (1956-09-01), Van Dijk et al.
patent: 2844599 (1958-07-01), Rendall et al.
patent: 3259561 (1966-07-01), Sievers
patent: 3454664 (1969-07-01), Siddiqui et al.

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