Process for charging silver electrodes to monoxide level

Chemistry: electrical and wave energy – Processes and products

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204 57, H01M 1044

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active

044616775

ABSTRACT:
A method of charging silver electrodes in which an electrode of porous sintered silver is anodized in the conventional manner in alkaline electrolyte to the so-called peroxide level and usually beyond, into the oxygen-evolution level, where the majority of the silver has been electroformed into divalent silver oxide. The charged electrode is then permitted to wet stand in the electrolyte or other alkaline solution to allow the residual unanodized silver in the electrode to convert a portion of the divalent silver oxide to monovalent silver oxide by a reverse disproportionation reaction.

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patent: 4078127 (1978-03-01), Megahed et al.
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patent: 4101719 (1978-07-01), Uetani et al.
patent: 4121021 (1978-10-01), Ogawa et al.
patent: 4250234 (1981-02-01), Langan
Publication "Reverse Disproportionation of AgO", by T. Katan et al., Abstt No. 69, pp. 173, 174, Oct. 11-16, 1981, Extended Abstracts of Battery Division, The Electrochemical Society, Inc.

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