Process for catalytically reducing nitroaromatic compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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260465E, 544305, 546171, 546311, 546 88, 564 88, 564305, 564336, 549 68, 549481, C07D21538, C07D21172, C07D23902

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045351627

ABSTRACT:
A process is herein described for catalytically reducing nitroaromatic compounds by displacement of hydrogen from carbon monoxide and water or from synthesis gas to nitroaromatic compounds, the catalytic reduction being catalyzed by complexes of rhodium, iridium, ruthenium and osmium; said process is characterized in that the CO+H.sub.2 O system or the (CO+H.sub.2)+H.sub.2 O system is caused to react with a nitroaromatic compound of formula:

REFERENCES:
patent: 4290961 (1981-09-01), Mestroni et al.
patent: 4384981 (1983-05-01), Dines et al.
patent: 4414417 (1983-11-01), Mestroni et al.
Tetrahedron Letters, No. 37, pp. 3385-3388, 1971.
Journal of Molecular Catalysts 12 (1981), pp. 385-387.

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