Chemistry: electrical and wave energy – Processes and products
Patent
1988-10-17
1990-03-20
Niebling, John F.
Chemistry: electrical and wave energy
Processes and products
204129, 204294, 502166, 502168, B25B 130, C25B 900
Patent
active
049099116
ABSTRACT:
Dirhodium complexes such as tetrakis(.mu.-2-anilinopyridinato)dirhodium are used in the catalytic reduction of dioxygen. An electric potential is applied to the dirhodium complex either dissolved in solution or supported by an electrode.
REFERENCES:
patent: 4451270 (1984-05-01), Roman et al.
patent: 4652647 (1987-03-01), Schlosberg et al.
S. E. Creager and R. W. Murray, "Electrochemical Reactivity of Manganese (II) Porphyrins, Effects of Dioxygen, Benzoic Anhydride, and Axial Ligands," 26, Inorg. Chem., 2612 (1987).
J. L. Bear, L. N. Liu and K. M. Kadish, "Structural, ESR, and Electrochemical Properties of Two[Rh.sub.2 (Ap).sub.4 ].sup.+ Geometric Isomers (ap=2-Anilinopyridinate), A True Mixed-Valent Rhodium (III) Complex," 26, Inorganic Chem., 2927-9 (1987).
E. S. Takeuchi and R. W. Murray, "Metalloporphyrin Containing Carbon Paste Electrodes," 188, J. Electroanal. Chem., 49-57 (1985).
D. A. Tocher and J. H. Tocher, "Synthesis and Spectro-electrochemical Characterization of a Novel Rhodium (II) Dimer, Rh.sub.2 (phNpy).sub.4 ", 104, Inorganica Chimica Acta, L15-L17 (1985).
Calabrese et al., (1983), J. Am. Chem. Soc., 105:5594-5600.
Bear John L.
Chao-Liang Yao
Gorgos Kathryn
Niebling John F.
University of Houston
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