Mineral oils: processes and products – Chemical conversion of hydrocarbons – Cracking
Patent
1992-05-28
1994-08-09
Pal, Asok
Mineral oils: processes and products
Chemical conversion of hydrocarbons
Cracking
585415, 585417, 585418, C07C 200, C10G 1105
Patent
active
053363930
ABSTRACT:
Catalytic conversion of organic compounds wherein catalysts come into contact with steam is performed efficiently by using a catalyst which comprises an MFI type zeolite having a ratio of SiO.sub.2 /(Al.sub.2 O.sub.3 +Ga.sub.2 O.sub.3) of 20 to 200 in molar ratio, a ratio of Ga.sub.2 O.sub.3 /Al.sub.2 O.sub.3 of 0 to 50 in molar ratio and a ratio of peak intensity of SiOH, I.sub.SiOH, to peak intensity of acidic OH, I.sub.H.sup.+, determined from .sup.1 H-NMR, I.sub.SiOH /I.sub.H.sup.+, of 0 to 0.5 and loses little catalytic activity on exposure to steam.
REFERENCES:
patent: 4761511 (1988-08-01), Barlow
patent: 4861934 (1989-08-01), Suzuki et al.
patent: 5073673 (1991-12-01), Hirabayashi et al.
Chemical Abstracts, vol. 107, No. 1, Jul. 6, 1987, Columbus, Ohio, Abstract No. 10256E, p. 181 of JP-A-62045539.
Chemical Abstracts, vol. 115, No. 20, Nov. 18, 1991, Columbus, Ohio, Abstract No. 211518F, Bandiera Jean et al; "On the enhanced dehydrogenation versus cracking ability of an acidic gallium-MFI: a tentative acid-base interaction model".
Masunaga Hiroharu
Sawa Masahiko
Takatsu Kozo
Wakushima Yasushi
Idemitsu Kosan Co. Ltd.
Pal Asok
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