Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1981-07-23
1982-11-09
Lone, Werren B.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568474, 568472, 568471, C07C 47052, C07C 47055
Patent
active
043586236
ABSTRACT:
In catalytically oxidizing methanol in the vapor phase according to already-known processes for the production of formaldehyde, the hot formaldehyde-containing gaseous effluent of the catalytic converter is rapidly cooled by being passed through the tubes of a heat exchanger which are filled with balls composed of a solid which is substantially inert toward formaldehyde. As compared with a similar cooling system in which the tubes are empty or in which enhancement of heat transfer is attempted by using metal heat-transfer enhancement devices such as twisted metal ribbons, the present method affords reduced post-reaction decomposition of formaldehyde while at the same time allowing use of a relatively high temperature on the shell side of the heat exchanger whereby it becomes possible to raise steam at a pressure higher than that characteristic of the prior art.
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Kirk-Othmer, "Ency. of Chem. Tech.", vol. 11, Third ed. p. 233, John Wiley & Sons.
McMillan William P.
Murphy Carl D.
Celanese Corporation
Lone Werren B.
Pritchett R. M.
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