Process for catalytic epoxidation of olefinic compounds, novel c

Details Process for catalytic epoxidation of olefinic compounds, novel c Process for catalytic epoxidation of olefinic compounds, novel c

1996-01-11

1998-06-09

Ivy, C. Warren

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

502172, C07D32100

Patent

active

057636230

ABSTRACT:
Methods for effecting epoxidation of olefinic compounds using cyclic ketone catalysts is provided. In particular, catalytic asymmetric epoxidation of unfunctionalized olefins, e.g., trans-olefins and trisubstituted olefins using novel cyclic ketones possessing C.sub.2 symmetric chiral elements is provided.

REFERENCES:
Kurihara, M., et al. "Stereoselective Eposidation with Dioxiranes from Generated Ketones", Tet. Let., 35 (10), pp. 1577-1580, Mar. 1994.
Yang, D., et al. "Epoxidation of Olefins Using Methyl(trifluoromethyl)dioxirane Generated in Situ", J. Org. Chem, 60, pp. 3887-3889, Jun. 1995.
Denmark, S.E., et al. "Catalytic Epoxidation of Alkenes wih Oxone ", J. Org. Chem., 60, pp. 1391-1407, Mar. 1995.

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