Process for catalytic dehydration of ethanol vapor to ethylene

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

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C07C 100

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044232705

ABSTRACT:
Process for catalytic dehydration of ethanol vapor to ethylene is provided which is carried out in the presence of water vapor, the mixture of ethanol and water vapor being contacted with the catalyst bed containing a substituted phosphoric acid catalyst. The catalyst comprises a catalyst support having absorbed thereon a substituted phosphoric acid in which one of the hydroxyl groups thereof has been replaced by a hydrophobic organic group containing from 4 to 22 carbons.

REFERENCES:
patent: 2220430 (1940-11-01), Stanley
patent: 2569092 (1951-09-01), Deering
patent: 3388181 (1968-06-01), Anspon
Pearson et al., Ind. Eng. Chem. Prod. Res. Dev., 19, 245-250 (1980).

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