Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1978-01-18
1980-03-18
Lone, Werren B.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
252431P, C07C 4508
Patent
active
041939425
ABSTRACT:
Olefinically unsaturated compounds are subjected to hydroformylation to produce the corresponding aldehyde having an additional carbon atom by reacting the compound with hydrogen and carbon monoxide under appropriate conditions of temperature and pressure in the presence of a catalytically active metallo-organic complex in the pores of a solid porous carrier in the form of a solution in a ligand-forming electron-donating phosphorous compound, such as triethyl phosphine, that has a vapor pressure of less than 15 mbar under reaction conditions. The central atom of the metallo-organic complex is preferably rhodium, cobalt, ruthenium or irridium.
REFERENCES:
patent: 3733362 (1973-05-01), Biale
patent: 3937742 (1976-02-01), Yoo
patent: 3940447 (1976-02-01), Yoo
patent: 3989759 (1976-11-01), Yoo
Gerritsen Leendert A.
Scholten Joseph J. F.
Lone Werren B.
Stamicarbon B.V.
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