Process for applying thermal barrier coatings to metals

Metal treatment – Compositions – Heat treating

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148 635, 4273764, 4273768, C23C 1100

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044837208

ABSTRACT:
Process for applying a protective coating to a metal substrate which provides a thermal barrier and a barrier against oxidation of the substrate. The coating material is a mixture of two metals M.sub.1 and M.sub.2, e.g., cerium (M.sub.1) and cobalt (M.sub.2), one of which when exposed to an atmosphere containing a low partial pressure of oxygen and at a high temperature forms a stable oxide, the other of which does not form a stable oxide under such conditions. A coating consisting of such a metal alloy or mixture is subjected to such conditions to produce an outer oxide layer of metal M.sub.1 and an inner metal layer of M.sub.2 alloyed with one or more components of the substrate. The oxide layer provides thermal and oxidation protection and the inner layer bonds the coating to the substrate.

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Jorgensen, "Oxidation-Controlled Aging of SmCo.sub.5 Magnets", Journal of the Less-Common Metals, vol. 77 (1981) pp. 221-226.
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Bartlett et al., "Microstructure and Growth Kinetics of the Fibrous Composite Subscale . . . " Metallurgical Transactions, vol. 5, Feb. 1974.
Bartlett et al., "Microstructural Changes in SmCo.sub.5 Caused by Oxygen Sinter-Annealing and Thermal Aging", J. of the Less-Common Metals, vol. 37, 1974, pp. 21-34.
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