Process for an anionic melt polymerization of caprolactam with i

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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524606, 525178, 525183, 525184, 525421, 525424, 525426, 528323, 528325, 528326, C08G 6918

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active

050397842

ABSTRACT:
A process for the continuous and discontinuous production of polycaprolactam is disclosed which includes the step of polymerizing, by anionic polymerization, .epsilon.-caprolactam to which suitable initiators and activators are added. The process may optionally include the addition of comonomers, pigments, electroconductive fillers, modifying polymers, inorganic fillers, reinforcing fibers, inorganic fillers and/or other additives to a dispersing media in which the polymerization takes place with polycaprolctam, copolymers or composites thereof being obtained in the form of particles. The foregoing additives may, for example, be added to the dispersing media dropwise with mechanical or convective stirring under controlled temperature conditions. The granulometric or morphological characteristics of the particles obtained are influenced by the nature, viscosity, temperature and the rate of stirring of the dispersing medium, as well as by the rate of feed of the caprolactam and the polymerization ingredients to the dispersing media and by the geometry of the polymerization reactor.

REFERENCES:
patent: 3017391 (1962-01-01), Mottus et al.
patent: 3061592 (1962-10-01), Schnell et al.
patent: 3298977 (1967-01-01), Robertson
patent: 3910861 (1975-10-01), Wolvers et al.
patent: 4017465 (1977-04-01), Bacskai
patent: 4309530 (1982-01-01), Bour et al.

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