Process for an addition reaction of organic silicon...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

Reexamination Certificate

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C528S025000, C528S031000

Reexamination Certificate

active

10857660

ABSTRACT:
The invention relates to a process for the preparation of polyorganosiloxanes and polyorganosilanes of high purity by an addition reaction of siloxanes and/or silanes which contain at least one H—Si group with compounds having olefinic double bonds in the presence of a platinum catalyst and optionally further additional components, wherein the reaction is carried out in the presence of a platinum(0)complex catalyst which was dissolved in a solvent before addition to the reaction medium and to whose solution an effective amount of at least one unsaturated hydrocarbon having 2 to 6 carbon atoms was added.

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Noll, Walter; “Chemie und Technologie der Silicone”, 1968, Verlag Chemie, GmbH, p. 43.
Fleming, Ian; “Grenzorbitale und Reaktionen Organischer Verbindungen”, 1979, Verlag Chemie, Weinheim, New York, pp. 136-137.
Steffanut, Pascal, et al; “Efficient Homogeneous Hydrosilylation of Olefins by Use of Complexes of Pt0With Selected Electron-Dificient Olefins as Ligands”; Chem, Eur. J., 1998, 4, No. 10, pp. 2008-2017.
Houk, K. N.; “Generalized Frontier Orbitals of Alkenes and Dienes; Regioselectivity in Diels-Alder Acivity”; Journal of the American Chemical Society, 98:12, Jun. 13, 1973, pp. 4092-4094.
Sahgal, A., et al.; “Solubility of Ethylene in Several Polar and Non-Polar Solvents”; The Canadian Journal of Chemical Engineering, Jun. 1978, vol. 56, pp. 354-357.

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