Process for alkylating hydrocarbons

Chemistry of hydrocarbon compounds – Saturated compound synthesis – By condensation of a paraffin molecule with an olefin-acting...

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585709, 585721, 585730, 585731, 502 30, 502 31, 502 53, 502 56, C07C 258, C07C 256, B01J 2034

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059861584

ABSTRACT:
The invention pertains to a process for alkylating hydrocarbons in which an alkylatable organic compound is reacted with an alkylation agent to form an alkylate in the presence of a catalyst comprising a hydrogenating function and a solid acid constituent, with the catalyst being subjected intermittently to a regeneration step by being contacted with a feed containing a saturated hydrocarbon and hydrogen, said regeneration being carried out at 90% or less of the active cycle of the catalyst, with the active cycle of the catalyst being defined as the time from the start of the feeding of the alkylation agent to the moment when 20% of the alkylation agent leaves the catalyst-containing reactor section without being converted, not counting isomerization inside the molecule. The process according to the invention is especially attractive for the alkylation of isobutane with one or more butenes to form an alkylate with a high RON.

REFERENCES:
patent: 3549557 (1970-12-01), Bolton et al.
patent: 3851004 (1974-11-01), Yang
patent: 5489732 (1996-02-01), Zhang et al.
Abstract, EP 688749-A1, dated Dec. 27, 1995 .
International Search Report, dated Jun. 23, 1997.

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