Process for alkylating aromatic hydrocarbons and catalyst theref

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260671B, 260671P, 260671R, C07C 352

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active

039924670

ABSTRACT:
Alkylatable aromatic hydrocarbons are alkylated with olefins and alkylhalides under anhydrous alkylating conditions in the presence of a metallic cation exchanged trioctahedral 2:1 layer-lattice smectite-type catalyst in which the metallic cation has a Pauling electronegativity greater than 1.0. In a specific embodiment, 1-dodecene is reacted with benzene by contacting the dodecene and benzene under anhydrous conditions in the liquid phase at the boiling point of the mixture with a catalyst comprising a metallic cation such as Al.sup.3.sup.+, In.sup.3.sup.+ and Cr.sup.3.sup.+ exchanged onto the surface of hectorite clay.

REFERENCES:
patent: 2853533 (1958-09-01), Weaver
patent: 2930819 (1960-03-01), Aries

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