Process for acylation of amino, imino and hydroxyl groups using

Details Process for acylation of amino, imino and hydroxyl groups using Process for acylation of amino, imino and hydroxyl groups using

1974-09-25

1976-06-01

Gotts, Lewis

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260239A, 260243R, 260244R, 2602472R, 2602475R, 260250R, 260251QB, 260269, 260290R, 260302R, 2603067R, 260307R, 260309, 2603131, 260327R, 260333, 260471R, 260479R, 260482R, 260558R, 260558H, 260558S, 260558A, 260561R, 260561A, 260561H, 260561S, 260561HL, 260562R, 260562H, 260562N, 260562B, 260562P, C07C10352, C07C 6900, C07C12500

Patent

active

039608298

ABSTRACT:
Pyrimidine derivatives represented by the formula, ##SPC1##
Wherein R.sub.1 and R.sub.2 are individually a hydrogen atom or a methyl group, and R.sub.3 is a group formed by removing the carboxyl group from a carboxylic acid, are quite useful in acylating compounds having amino and/or imino and/or hydroxyl groups. The pyrimidine derivatives can easily be prepared by reacting a 2-mercapto-4- and/or 6-methyl-substituted or unsubstituted pyrimidine with a carboxylic acid or a reactive derivative thereof in an inert solvent.

REFERENCES:
schroder and Lubke, "The Peptides," vol. 1, Academic Press, New York, 1965, pp. 105-108.
Farrington et al., J. Chem. Soc., 1957, pp. 1407-1413.

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