Process for a two stage melt polymerization for the...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

Reexamination Certificate

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C528S310000, C528S335000, C528S336000, C528S337000, C528S339000, C528S340000, C528S353000, C528S342000, C528S348000

Reexamination Certificate

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07060782

ABSTRACT:
A process for the production of high molecular weight polybenzimidazole by one: providing a first reaction vessel; charging the reaction vessel with at least one aromatic hydrocarbon tetraamine, and a heterocylic ring making up the dicarboxylic component; heating the reactants under agitation in a substantially oxygen-free atmosphere with agitation until the agitator torque is about 1.5 times the torque before a rise in viscosity begins; terminating the agitation while continuing to heat the reaction mixture to about 230° C. while allowing the reaction mass to foam; cooling the reaction mass to a friable foamed mass; crushing the friable foamed mass to obtain a ground prepolymer; and two: providing a second reaction vessel, the second reaction vessel being a high intensity reaction vessel; transferring the ground prepolymer to the second reaction vessel; heating the ground prepolymer under agitation to over 315° C. at atmospheric pressure for a time of about 90 minutes.

REFERENCES:
patent: 4588808 (1986-05-01), Ward
patent: 4672104 (1987-06-01), Ward
patent: 4717764 (1988-01-01), Ward
patent: 5171829 (1992-12-01), Uekita et al.
patent: 2006/0004181 (2006-01-01), Dawkins et al.
patent: 2006/0004182 (2006-01-01), Dawkins et al.

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