Process for a passivating postrinsing of conversion layers

Metal treatment – Process of modifying or maintaining internal physical... – Processes of coating utilizing a reactive composition which...

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148243, 148255, 148256, 148257, 205194, 205197, C23C 2283

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active

052942660

ABSTRACT:
The invention is in a composition and process for the chromium free passivating postrinsing of conversion layers on metals before the application of a paint or adhesive. The conversion layers can be on the bases of phosphate layers, at least two polyvalent metal ions with complex formers, titanium, zirconium and/or hafnium. The postrinsing agent is an aqueous solution which has been adjusted to a pH value of up to 5 and which contains an aluminum fluorozirconate having an Al:Zr:F mole ratio of (0.15 to 8.0):1:(5 to 52), and in which solutions the total concentration of Al+Zr+F is 0.1 to 8.0 g/l. The postrinsing solutions may additionally contain at least one of the anions benzoate, caprylate, ethyl hexoate, salicylate in a total concentration of 0.05 to 0.5 g/1 and may preferably be adjusted to the required pH value with cations of volatile bases, such as ammonium, ethanolammonium and di- and triethanolammonium. The paint is subsequently applied suitably by cathodic electrocoating or powder coating or from a low-solvent high-solids paint.
The rinsing treatment is over a period of 1 to 120 seconds at temperatures of 20.degree. to 80.degree. C. The invention is used as a pretreatment to the application of a paint coating, film coating or adhesive coating.

REFERENCES:
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F. A. Lowenheim, Electroplating, McGraw-Hill Book Co., New York, 1978, p. 442.
"Coating of Metals with Silianes", Nihon Parkerizing Co., Ltd., Jpn. Tokkyo Koho JP 59 64,781, Apr. 12, 1984, (Japanese counterpart of EP 153 973) (Abstract English translation).

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