Process for a isotactic/syndiotactic polymer blend in a single r

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502113, 502117, 502152, 526114, 526119, C08F 464

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active

056438460

ABSTRACT:
The present invention is a process for producing a catalyst system to produce polymer blends in a single reactor, polymer blends of isotactic polyolefins and syndiotactic polyolefins. The catalyst system is a combination of at least one metallocene catalyst and at least one conventional supported Ziegler-Natta catalyst. The multi-catalyst system is obtained by mixing the components of at least one metallocene catalyst and at least one conventional supported Ziegler-Natta catalyst. The metallocene catalyst comprises a metallocene compound and an ionizing agent. The conventional supported Ziegler-Natta catalyst comprises an aluminum alkyl and a transition metal compound with, optionally, an electron donor.

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J. Am. Chem. Soc. 1988, 110, 6255-6256, Ewen et al, "Syndiotactic Propylene Polymerization with Group 4 Metallocene".
International Symposium on Recent Developments in Olefin Polymerization Catalyst, 1988, pp. 501-515, Keii et al. "Catalyst Olefin Polymerization".
Hackh's Chemical Dictionary, 5th Edition. p. 24, 1987.

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