Specialized metallurgical processes – compositions for use therei – Compositions – Loose particulate mixture containing metal particles
Reexamination Certificate
2000-10-26
2002-04-02
Mai, Ngoclan (Department: 1742)
Specialized metallurgical processes, compositions for use therei
Compositions
Loose particulate mixture containing metal particles
C075S355000
Reexamination Certificate
active
06364928
ABSTRACT:
The present invention relates to a process for producing atomized metal powder in an atomization plant comprising a casting box, a reactor vessel, a powder container and sedimentation equipment. The invention also relates to the atomization plant, atomized metal powder produced according to the process and the use of the metal powder.
One of the problems in manufacturing atomized metal powder is that the thermal balance in the reactor is not in balance and that critical temperatures occur. This entails increased risk of explosion since the firing temperature and partial pressure are reached in uncontrolled manner.
Another problem is that if the pressure of the spray coolant is too high the powder particles will be deformed, becoming uneven and pointed in shape. High temperature of the spray coolant also causes the formation of waves on the surface of the liquid.
The object of the present invention is to provide a solution to these problems. According to the invention they are solved by introducing atomizing medium into the reactor vessel via primary nozzles in the upper part of the reactor. Coolant is then supplied at low pressure via at least one secondary supply arrangement in the upper part of the reactor vessel, arranged in combination with the nozzles for atomizing medium. Coolant and atomizing medium are withdrawn from the lower part of the reactor and then recirculated via a number of transport arrangements and sedimentation equipment. Some of the metal powder is removed directly from the reactor, down into a powder container. The rest of the metal powder is separated through sedimentation in sedimentation equipment.
The embodiment described above, and other embodiments of the invention, are defined in the dependent claims.
DESCRIPTION OF THE INVENTION
From a casting box a stream of molten metal, preferably steel, flows into the reactor vessel. The stream is disintegrated by atomizing medium flowing under high pressure from primary nozzles in the upper part of the reactor. Secondary coolant is allowed to flow under low pressure from at least one annular extruder in connection with the primary nozzles. The coolant flows down through the gas chamber of the reactor vessel and forms cooling curtains. The gas-filled part of the reactor is therefore smaller than the corresponding gas chamber in conventional atomizing plants. Large quantities of coolant at low pressure achieve efficient cooling of the powder particles without them become deformed. They retain their spherical shape since the thrust with which the coolant encounters the particle surface is limited. The desired final product is thus obtained and at the same time the thermal balance necessary for safety of the process is also achieved. Wave formation is greatly suppressed through the supply of secondary coolant through the annular extruders and the variation in the path of the powder particles from vortex to liquid surface is thus reduced.
In order to attain constant conditions in the reactor vessels the coolant balance must be at equilibrium during the atomizing period. The same amount of coolant must be removed from the reactor vessel as is supplied during the same time period. The falling rate of metal powder with a size of 100&mgr; is in the order of magnitude a few cm/sec. So that the reactor plant does not become unreasonably large the bottom of the reactor vessel has been provided with an inner cone so that the powder formed is guided down through the bottom outlet and into a powder container, known as a wet container. The coolant is sucked out via a specially shaped suction chamber arranged in the lower part of the reactor vessel. Only marginal quantities of powder particles larger than 100&mgr; are drawn out through this suction chamber. Particles smaller than 100&mgr;, preferably smaller than 50&mgr;, are carried out with the coolant. Powder of such small particle size is very attractive for certain purposes and it is therefore important that this fraction can be salvaged in a simple and efficient manner without extra work operations. This can easily be achieved by allowing the coolant withdrawn to sediment in at least two cylindrical sedimentation containers having conical bottoms. The inclination of the cones shall at least exceed the angle of repose of the powder.
The sedimentation container is dimensioned with a good margin to hold the coolant and atomizing medium required for one charge of powder in the atomizing process. The height and diameter of the container must be optimized to allow all powder particles larger than 20&mgr; to have time to settle between two charges. The inlet for coolant and atomizing medium into the container shall also be designed and placed to facilitate sedimentation. From the above, therefore, it is evident that at least two sedimentation containers are necessary for the atomizing process. The coolant withdrawn passes a suction pump. Since the sedimentation container holds the coolant and atomizing medium requirement for a full charge, atomization and subsequent cooling of the powder occurs down to solidification temperature with exactly the same cooling and atomizing medium temperature throughout the charge. This results in a powder with optimal reproducibility with regard to atomizing, particle shape and distribution of carbon in the powder produced.
The coolant is introduced into a storage tank having an inlet part in the form of a sedimentation basin. The sedimented powder particles, the majority of which are smaller than 100&mgr;, are collected in a separate wet container. The coolant freed from powder is recirculated to the reactor vessel via a heat exchanger and with the aid of high-pressure pumps through the spray nozzles as atomizing medium and through the annular extruders as secondary coolant, respectively.
The part-functions described above cooperate to produce an efficiently operating atomization plant with great flexibility with regard to the properties and shape of the powder produced.
A small quantity of the atomizing medium, which preferably consists of acyclic and/or isocyclic hydrocarbon compounds such as paraffin or diesel oils, is carbonized to carbon and hydrogen in the atomizing process. This carbon is completely absorbed by the powder particles, primarily in their outer layer. This causes the metal particles to have increased content of carbide-bound carbon in the outer layer. The hydrogen formed at carbonization increases the pressure in the gas part of the reactor and must therefore be removed. This is achieved via a liquid lock.
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Axmin Erik
Larsson Rutger
Mai Ngoclan
Ostrolenk Faber Gerb & Soffen, LLP
Rutger Larsson Konsult AB
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