Process and intermediates for the production of...

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Cyclopentanohydrophenanthrene ring system doai

Reexamination Certificate

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C514S170000, C514S177000, C552S558000

Reexamination Certificate

active

07947667

ABSTRACT:
A process for preparing an intermediate compound of formula (II)where X is as defined in the specification, R1is haloalkyl, alkyl, alkenyl, cycloalkyl, carboxyalkyl, alkoxycarbonylalkyl, aryl or arylalkyl;R2, R3, R4and R5are organic groups as defined in the specification, which process comprises aromatisation of a compound of formula (III)where R1, R2, R3, n, X and R5are as defined in relation to formula (II) and R4′is a group R4or a precursor group thereof, and thereafter if necessary or desired, carrying out one or more of the following steps: (i) removing any hydroxy-protecting groups R; (ii) converting a precursor group R4′to a group R4, or where R4′is a group R4, converting it to a different such group.Compounds obtained are useful intermediates for example in the preparation of fulvestrant. Novel intermediates are also claimed.

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