Process and composition for purifying arsine, phosphine, ammonia

Catalyst – solid sorbent – or support therefor: product or process – Solid sorbent – Organic

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502402, 502415, 502416, 502400, 423304, 521 28, 521 31, 521 52, 521 53, 525366, B01J 2004, B01J 2016, B01J 2022

Patent

active

047613955

ABSTRACT:
A process for purifying a gaseous mixture comprising arsine, phosphine, ammonia, and/or inert gases, to remove Lewis acid and/or oxidant impurities therefrom, comprising contacting the mixture with a scavenger including a support having associated therewith an anion which is effective to remove such impurities, such anion being selected from one or more members of the group consisting of: (i) carbanions whose corresponding protonated compounds have a pK.sub.a value of from about 22 to about 36; and (ii) anions formed by reaction of such carbanions with the primary component of the mixture.

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