Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – For cleaning a specific substrate or removing a specific...
Reissue Patent
1999-06-11
2002-02-19
Raymond, Richard L. (Department: 1624)
Cleaning compositions for solid surfaces, auxiliary compositions
Cleaning compositions or processes of preparing
For cleaning a specific substrate or removing a specific...
C510S331000, C510S491000, C510S500000, C510S505000, C510S515000, C510S520000, C544S001000, C544S052000, C544S103000, C544S223000, C564S204000, C564S205000, C564S215000, C564S291000, C564S292000, C564S294000, C564S296000
Reissue Patent
active
RE037555
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The invention relates to a method of producing a mixture of a quaternary ammonium compound, fatty acid, fatty acid ester and tertiary amine salt in situ which is a highly functional mixture that is manufactured in a single step reaction whereby quaternization is completed without the aid of solvents, especially flammable solvents. The single step reaction process eliminates separate blending of individual components.
2. Brief Description of the Prior Art
The preparation of quaternary ammonium compounds is usually conducted in stainless steel or glass-lined equipment to which a tertiary amine is charged and a solvent. Flammable solvents such as isopropyl alcohol are generally used although mixtures of isopropyl alcohol and water sometimes are employed or water alone is used. Flammable solvents are also undesirable because they are a fire hazard and special handling procedures are required when they are used. In many applications, these solvents have to be stripped from the mixture when the reaction is completed because the ultimate use of the product is in a solventless or solid form.
After the reactants are loaded into the reactor they are heated to a temperature of about 50 to about 100° C. after which a quaternizing reagent is added. In some instances an exotherm is produced as a result of the quaternizing reaction and the reactor and its contents have to be cooled. The rate of addition of the quaternizing agent can also be controlled in order to minimize or eliminate the exotherm. As noted previously, in some instances, the solvent, if any is employed in the quaternizing reaction is stripped from the quaternary ammonium compound obtained since some commercial uses for the compounds are in solventless systems. Additionally, bulk shipments of quaternary ammonium compounds with solvents adds to transportion costs which is another reason to remove the solvents.
The largest use for quaternary ammonium compounds is as a fabric softener and presently accounts for more than about three quarters of the total market for these material. Some fabric softeners are supplied as a liquid dispersion of from about 3% to about 10% by weight of the quaternary ammonium compound which is adapted to be added during the rinse cycle of a commercial or home laundering operation. Another significant fabric softening application is the utilization of quaternary ammonium compounds in combination with a substrate such as a nonwoven fabric or a polymeric foam such as a polyurethane foam, this substrate so treated being added to a fabric dryer such as a clothes dryer while the fabric or clothes are still damp. The quaternary ammonium compound is formulated usually with a fatty acid ester which promotes the transfer of the quaternary ammonium compound from the nonwoven or porous polymeric substrate to the fabric or clothes.
Lastly, quaternary ammonium compounds are now being added to both solid and liquid laundry detergent compositions so that the quaternary ammonium compound can be incorporated as a fabric softener during the wash cycle of fabrics or clothes. The most successfully utilized quaternary ammonium compounds in this last respect are the dimethyl (dihydrogenated tallow) ammonium chlorides or methyl sulfates. Other quaternary ammonium compounds such as imidazolines and amidoamine quaternaries are also used in this regard.
Where the quaternary ammonium compound is used on a substrate for transfer to fabric or clothing in a fabric or clothes dryer, it has generally been the practice to separately blend the fatty acid ester into the quaternary ammonium compound which involves the extra manufacturing steps of transportion, handling and blending of the fatty acid esters into the quaternary ammonium compounds. If these steps can be eliminated a cost savings could be realized.
Quaternary ammonium compounds are also used to manufacture organomodified clays which may be added to drilling muds utilized in drilling oil wells, the organomodified clay providing improved lubrication and rheological properties of the drilling muds. These organoclays are also employed as thixotropic agents in plastisols, organosols, paints and other protective coatings, grease additives, foundry additives, cosmetics, resins and printing inks. The most common quaternary ammonium compounds employed in this regard are methyldi(hydrogenated tallow) benzylammonium chloride, dimethyldi(hydrogenated tallow) ammonium chloride and dimethyl(hydrogenated tallow) benzylammonium chloride.
Quaternary ammonium compounds are also employed as bactericides the most common of which is the quaternary ammonium compound of benzylchloride and a dimethylalkylamine, the alkyl group having from about 12 to about 16 carbon atoms as well as trimethyl alkyl ammonium chlorides where the alkyl group is a long chain alkyl such as an octadecyl group. Additionally, dimethyldicoconut-oil fatty ammonium chlorides are also effective disinfectants e.g. bactericides or bacteristats, especially against anaerobic bacteria which are sulfate reducers that are found in oil wells, these bacteria causing severe corrosion problems and plugging of formations which this type of quaternary ammonium compound can minimize or eliminate. Additionally, these quaternary ammonium compounds effective against anaerobic bacteria are also effective in removing oil from sand stone formations in oil wells and provide a two-fold effect or functioning not only as a bactericide but also in promoting so-called secondary recovery of oil.
An additional use of quaternary compounds is in hair treatment because of the antistatic effects obtained with such compounds, as well as the increased wetting which promotes improvements in both wet and dry combing or brushing and improves luster and feel. The most commonly used quaternary ammonium compounds in this respect are trimethylalkylammonium chloride, pentaethoxystearylammonium chloride, dimethylstearylbenzylammonium chloride and dimethyldialkylammonium chlorides.
It is therefore an object to overcome these and other difficulties encountered in the prior art.
It is also an object of the present invention to provide a method for manufacturing a mixture of quaternary ammonium compounds with a fatty ester inter allia which can be used in fabric softening applications. It is also an object of the present invention to provide such mixtures.
It is a further object of the invention to provide mixtures of quaternary ammonium compounds with fatty acid esters, amine salts and fatty acids that can be employed in any or all of the foregoing applications.
These and other objects have been achieved according to the present invention which will be further understood in view of the following description and claims.
SUMMARY OF THE INVENTION
It has been found that a highly functional mixture of a quaternary ammonium compound, a fatty acid ester, an ammonium salt and a fatty acid can be obtained in a single step reaction without the aid of solvents, especially flammable solvents to thereby produce a mixture of highly functional components. The single step reaction thereby eliminates the separate blending of such individual components as the fatty acid ester, the ammonium salt and the fatty acid with the quaternary ammonium compound.
The advantage of the method of the present invention is that it provides a composition that is non-flammable and it is ready to be flaked or powdered because of its bulk form and can be used as a fabric softener, a fabric lubricant, a hair condition as well as an anti-static agent that can be released from a substrate such as a nonwoven fabric or a polymeric foam. These mixtures can also be used in combination with synthetic detergents or as lubricant, an emulsifier, in cosmetic preparations hair conditioning components clay modifiers, bactericidal compositions and as a floculant.
REFERENCES:
patent: 2474202 (1949-06-01), Rust
patent: 2583772 (1952-01-01), Gunderson
patent: 3686025 (1972-08-01), Morton
patent: 3936537 (1976-02-01), Baskerville, Jr. et al.
patent: 4022938 (1977-05-01), Z
Ackerman Jeannene A.
Miller Michael
Whittlinger David E.
Goldschmidt Chemical Company
Raymond Richard L.
Scully Scott Murphy & Presser
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